• 2022-06-07 问题

    If the carbonyl group is at an end of the carbon chain (that is, in an aldehyde group), the monosaccharide is an aldose; if the carbonyl group is at any other position (in a ketone group), the monosaccharide is a _________.

    If the carbonyl group is at an end of the carbon chain (that is, in an aldehyde group), the monosaccharide is an aldose; if the carbonyl group is at any other position (in a ketone group), the monosaccharide is a _________.

  • 2022-06-06 问题

    Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? A: The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. B: Aldehydes are more sterically hindered than esters. C: Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. D: Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic.

    Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? A: The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. B: Aldehydes are more sterically hindered than esters. C: Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. D: Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic.

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